However, significant structural changes of the capping layer due to the addition of N have LEE011 order been found to take place [14]. Strain and compositional inhomogeneities are induced during the CL growth, yielding a degradation of the luminescence such that, as far as we know, no room-temperature (RT) emission has been reported to date using such a CL. Nevertheless, the resulting morphology of the CL could be modified through the growth conditions. Growth parameters such as growth temperature or growth rate could significantly influence the mass transport phenomena and composition modulation. Therefore, a need arises to find the optimal growth conditions in order to exploit the promising properties

of this QD-CL system in optoelectronic applications. In this work, we study the effect of modifying the CL growth temperature, thickness, and growth rate on QD luminescence. RT photoluminescence (PL) is shown to be achievable through different growth conditions, and extending the emission to 1.3 μm is possible by means of the appropriate combination of the growth parameters. Methods All of the analyzed samples were grown by solid source molecular beam epitaxy on n +-doped GaAs (001) substrates. The QD layers were always grown under the same conditions by depositing 2.8 monolayers (ML) of InAs at 450°C and 0.04

ML s−1 on an intrinsic 0.5-μm-thick GaAs buffer layer. The GaAsSbN CL was grown under the reference conditions discussed below, modifying only one of the growth parameters for

each Talazoparib solubility dmso series of samples. A 250-nm-thick GaAs layer was grown on top of the GaAsSbN capping. Sb was supplied from an effusion cell, while active N was generated from a radio-frequency (RF) plasma source with a 0.1-sccmflow of pure N2. The samples were characterized by PL measurements at 15 K and RT. A He-Ne laser was used as the excitation source, and low-temperature (LT) measurements were done using a closed-cycle He cryostat. The emitted light from the samples was dispersed by a 1-m spectrometer and detected with a liquid nitrogen-cooled Ge detector through standard lock-in techniques. Results and discussion First, it is necessary to establish the reference growth conditions for the GaAsSbN CL as a starting point from which one of the parameters triclocarban will be modified in each series of samples. Thus, as reference conditions for the CL growth, those used in previous studies are considered [12], i.e., a 470°C growth temperature, a ratio of As4/Ga beam equivalent pressure of 32, a thickness of 5 nm, and a growth rate of 1 ML s−1. Regarding the N and Sb contents, a power of 140 W for the RF plasma source and a temperature of 335°C for the Sb effusion cell were chosen as reference source conditions. These conditions correspond in our system to nominal contents of 2.5% of N and 15% of Sb.